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Zr-MOF composites with zipped and unzipped carbon nanotubes for high-performance electrochemical supercapacitors


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Corresponding authors


a


Department of Chemistry, School of Science and Engineering, The American University in Cairo, Cairo, Egypt

E-mail:
ehab.elsawy@aucegypt.edu


b


Analysis and Evaluation Department, Egyptian Petroleum Research Institute (EPRI), 1 Ahmed El Zomor St., Nasr City, Cairo, Egypt


c


Central Analytical Laboratories, Nanotechnology Research, Egyptian Petroleum Research Institute (EPRI), 1 Ahmed El Zomor St., Nasr City, Cairo, Egypt


d


Department of Chemical Engineering, Kyung Hee University, Yongin-si, Gyeonggi-do, 17104 Republic of Korea

E-mail:
tyoon@khu.ac.kr

Abstract

Metal–organic frameworks (MOFs) have gained considerable interest as crystalline porous materials with notable characteristics, such as high surface area and excellent electrochemical performance, particularly in supercapacitor applications. The combination of MOFs with various nanocarbon materials further enhances their performance. This study investigated the combination of zirconium-based MOFs (Zr-MOFs) with graphene oxide nanoribbons (GONRs), zipped carbon nanotubes, and functionalized carbon nanotubes (FCNTs) to fabricate composites with elevated electrical conductivity, adjustable surface area, chemical robustness, mechanical strength, and customizable attributes for specific applications. Zr-MOFs exhibit remarkable capacitance, making them promising electrode materials for supercapacitors. GONRs and FCNTs have recently emerged as focal materials owing to their unique properties, which make them promising materials for electrochemical energy storage devices. A thorough investigation of the supercapacitive behavior of GONRs, FCNTs, Zr-MOFs, Zr-MOFs/FCNTs, and Zr-MOFs/GONRs in 1 M H2SO4 using different evaluation systems (three- and two-electrode systems) revealed a significant enhancement in the capacitance of Zr-MOFs after the introduction of GONRs and FCNTs. Employing Zr-MOF/GONR and Zr-MOF/FCNT composites as positive electrodes and GONRs as negative electrodes in two-electrode measurements demonstrated remarkable cycling stability by retaining their specific capacitances (Cs) even after 10 000 consecutive charge/discharge cycles at a high current density of 10 A g−1. Moreover, they feature a broad potential window of 1.7 V in the three-electrode system. This extends to 2 V in the two-electrode system, achieving high Cs. This highlights the remarkable electrochemical performance of the Zr-MOF/GONR and Zr-MOF/FCNT composites, offering a compelling approach for energy storage applications.

Graphical abstract: Zr-MOF composites with zipped and unzipped carbon nanotubes for high-performance electrochemical supercapacitors

Supplementary files

Article information

DOI
https://doi.org/10.1039/D4NR03926B

Article type
Paper

Submitted
25 Sep 2024

Accepted
30 Oct 2024

First published
20 Nov 2024


Nanoscale, 2024, Advance Article

Permissions



Zr-MOF composites with zipped and unzipped carbon nanotubes for high-performance electrochemical supercapacitors

A. R. Heiba, M. O. Abdel-Salam, T. Yoon and E. El Sawy,
Nanoscale, 2024, Advance Article

, DOI: 10.1039/D4NR03926B

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